Q. 65.0( 2 Votes )

Write the reactio

Answer :

(i) Clemmensen reduction

The carbonyl group of aldehydes and ketones is reduced to CH2 group on treatment with zinc amalgam (Zn-Hg) and concentrated hydrochloric acid (HCl).

>C=O >CH2 + H2O

(ii) Cannizzaro reaction

α hydrogen is the hydrogen attached to carbon which is immediately next to or attached to carbon of –C=O group in aldehydes.

So, aldehydes without α hydrogen undergo self oxidation and reduction in presence of concentrated alkali to give a molecule of alcohol (reduction) and a carboxylic acid salt (oxidation). For ex-

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