Q. 84.7( 3 Votes )
When a co-ordination compound is mixed with moles of are precipitated per mole of the compound. Write
A. Structural formula of the complex.
B. IUPAC name of the complex.
Since the number of moles of AgCl that is obtained are 2, there would be two Cl- ions satisfying the primary valencies, while there is presence of one Cl- ion and five H2O molecules inside the coordination sphere, resulting in a coordination sphere of 6, and one molecule of H2O being present as the molecule of hydration.
Structural Formula: [CrCl(H2O)5]Cl2.H2O
IUPAC name of the compound is Pentaaquachloridochromium(lll) chloride.
Rate this question :
How useful is this solution?
We strive to provide quality solutions. Please rate us to serve you better.
RELATED QUESTIONS :
Write down the IUPAC name for each of the following complexes and indicate the oxidation state, electronic configuration and coordination number. Also give stereochemistry and magnetic moment of the complex:
(i) K[Cr(H2O)2(C2O4)2].3H2O (iii) [CrCl3(py)3] (v) K4[Mn(CN)6]
(ii) [Co(NH3)5Cl-]Cl2 (iv) Cs[FeCl4]NCERT - Chemistry Part-I
Write all the geometrical isomers of [Pt(NH3)(Br)(Cl)(py)] and how many of these will exhibit optical isomers?NCERT - Chemistry Part-I
How many geometrical isomers are possible in the following coordination entities?
(i) [Cr(C2O4)3]3– (ii) [Co(NH3)3Cl3]NCERT - Chemistry Part-I
List various types of isomerism possible for coordination compounds, giving an example of each.NCERT - Chemistry Part-I
Draw the structures of optical isomers of:
(i) [Cr(C2O4)3]3– (ii) [PtCl2(en)2]2+
(iii) [Cr(NH3)2Cl2(en)] +NCERT - Chemistry Part-I
Using IUPAC norms write the formulae for the following:
(a) Potassium trioxalatoalumniate (III)
(b) Dichloridobis (ethane -1, 2-diamine) cobalt (III)Chemistry - Board Papers
When a coordination compound is mixed with 2 moles of AgCl are precipitated per mole of the compound. Write
(i) Structural formula of the complex
(ii) IUPAC name of the complexChemistry - Board Papers
Using IUPAC norms write the formulae for the following :
(a) Sodium dicyanidoaurate(I)
(b) Tetraamminechloridonitrito-N-platinum (IV) sulphateChemistry - Board Papers
A. For the complex write the hybridization, magnetic character and spin of the complex. (At. Number: Fe=26)
B. Draw one of the geometrical isomers of the complex which is optically active.Chemistry - Board Papers