C6H5CH2OH as the major product.
C6H5CH2NH2 reacts with HNO2 to form unstable diazonium salt, which in turn gives alcohol. Thus, when C6H5CH2NH2 reacts with HNO2 benzyl alcohol is formed along with N2 and H2O. The chemical reaction involved in this case is
When C6H5CH2NH2 reacts with HNO2 at low temperature, stable Diazonium salt is formed and no N2 gas is evolved in this case.
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