Answer :

(a) When heated, PCl5 sublimes but decomposes on stronger heating.

PCl5 + Heat PCl3 + Cl2

(b) Xenon fluorides react with fluoride ion acceptors to form cationic species and fluoride ion donors to form fluoro anions

SO when XeF2 reacts with PF5, the following reaction takes place

XeF2+ PF5 [XeF]+[PF6]-

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