Answer :
1. In distilled water: [H3O + ] × [OH-] = 10-14
For solution A, [H3O + ] = 10-14 ÷ [OH-]
= 10-14 ÷ (4.3 × 10-4)
= 2.32 × 10-11 M
For solution B, [H3O + ] = 7.3 × 10-10 M
•Since the hydronium ion concentration of solution B is more, so its pH will be less.
•The solution having the more pH will be more basic. As solution A will have more pH so it will be more basic.
2. using the relation, pOH + pH = 14
pOH = 14 – pH
= 14 – 9.3
= 4.7
Using, pOH = -log10[OH-]
4.7 = -log10[OH-]
log10[OH-] = -4.7
log10[OH-] = 5 -4.7 -5
log10[OH-] = -5 + 0.3
log10[OH-] = + 0.3
[OH-] = antilog
[OH-] = 1.99 × 10-5
3. molar mass of NaOH = atomic mass of Na + Atomic mass of O + atomic mass of H = 23 + 16 + 1 = 40g/ mol.
Volume of solution = 5 litres
Given weight = 8g
No. of moles = given weight ÷ molar mass
= 8g ÷ 40 g/mol
= 0.2 mole
Molarity = no. of moles ÷ volume in litres
= 0.2 ÷ 5
= 0.04 M
Therefore, the hydroxide ion concentration [OH-] = 0.04 M
pOH = -log10[OH-]
pOH = -log10[ 4 × 10-2]
pOH = 2 -log10[ 4]
pOH = 2- 0.6020 = 1.39
using, pOH + pH = 14
pH = 14 – pOH
pH = 14 - 1.39 = 12.61
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