Solution A will follow Raoult's law as it is an ideal solution. The intermolecular interactions of A–A and B–B type are nearly same as A–B type interactions.
Solution B will form a minimum boiling azeotrope and show a positive deviation from Raoult’s law.
Solution C will form a maximum boiling azeotrope and show a negative deviation from Raoult’s law.
Thus, Option(ii) is the correct answer.
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