Answer :

Explanation: The structure of methanol is CH3OH. To convert methanol to ethanoic acid (the number of carbon atoms is increasing from one carbon atom to two carbon atoms) we need ethanenitrile and we can get ethanenitrile from methyl chloride.

Note: If the number of carbon atoms is increasing, we need a nitrile group and if the number of atoms is decreasing, we need an amide group (Hoffman Bromamide reaction)

Step 1: Convert methanol into methyl chloride

Methanol (CH3OH) reacts with thionyl chloride (SOCl2) or PCl5 or PCl3 to form methyl chloride (CH3Cl) by the replacement of OH group by Cl atom.

Step 2: Convert methyl chloride into ethanenitrile

Methyl chloride (CH3Cl) reacts with ethanolic NaCN/ KCN to form ethanenitrile (CH3CN) by the removal of NaCl / KCl

Step 3: Convert ethanenitrile into ethanoic acid

Ethanenitrile (CH3CN) undergoes hydrolysis to form ethanoic acid (final product) which has one carbon atom more than the ethanenitrile.

Rate this question :

How useful is this solution?
We strive to provide quality solutions. Please rate us to serve you better.
Try our Mini CourseMaster Important Topics in 7 DaysLearn from IITians, NITians, Doctors & Academic Experts
Dedicated counsellor for each student
24X7 Doubt Resolution
Daily Report Card
Detailed Performance Evaluation
view all courses

(a) Write the reaChemistry - Board Papers