Q. 64.2( 41 Votes )

Give structures of the products you would expect when each of the following alcohol reacts with

(a) HCl –ZnCl2

(b) HBr and

(c) SOCl2.

(i) Butan-1-or (ii) 2-Methylbutan-2-ol

Answer :

(a)


(i) Primary alcohols do no react appreciably with Lucas’ reagent (HCl –ZnCl2) at room temperature.



(ii) Tertiary alcohol reacts immediately with Lucas ‘reagent.



(b) (i)



(ii)


(c) (i)



(ii)



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