Calculate e.m.f a

For given reaction we identify the oxidation and reduction half-cell reactions

For the cell as Ag²⁺ has positive reduction it tends to udergo reduction. For the given cell representation,

The emf of a cell is given by,

The emf of cell is 1.0796 V

The Gibbs free energy is given by,

The Gibbs free energy is ΔG = 208.4 kJ

OR

(a)

Given:

k = 1.06×10^-2 cm^-1

C = 0.1 M

To find: molar conductivity and degree of dissociation

We know that,

Molar conductivity is 106

Molar conductivity

Degree of dissociation

Degree of dissociation = 0.837

(b)