Q. 24

Calculate e.m.f a

Answer :

For given reaction we identify the oxidation and reduction half-cell reactions

For the cell as Ag2+ has positive reduction it tends to udergo reduction. For the given cell representation,

The emf of a cell is given by,

The emf of cell is 1.0796 V

The Gibbs free energy is given by,

The Gibbs free energy is ΔG = 208.4 kJ




k = 1.06×10-2 cm-1

C = 0.1 M

To find: molar conductivity and degree of dissociation

We know that,

Molar conductivity is 106

Molar conductivity

Degree of dissociation

Degree of dissociation = 0.837


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