Answer :

(a) The IUPAC names of the isomers of the complex are


cis- diamminedichloridoplatinum(II) and


trans- tiamminedichloridoplatinum(II)


(b) The formula for Tetraammineaquachloridocobalt(III) nitrate is [Co(NH3)4(H2O)Cl](NO3)2


The total oxidation no. of cationic part will be 3+0+0+(-1) = 2


(Since, NH3 i.e. ammineand H2O i.e. aqua are neutral ligands)


And the anionic part consists of NO3-. Therefore, the formula of complex is [Co(NH3)4(H2O)Cl](NO3)2.


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