Answer :

(a) The IUPAC names of the isomers of the complex are

cis- diamminedichloridoplatinum(II) and

trans- tiamminedichloridoplatinum(II)

(b) The formula for Tetraammineaquachloridocobalt(III) nitrate is [Co(NH3)4(H2O)Cl](NO3)2

The total oxidation no. of cationic part will be 3+0+0+(-1) = 2

(Since, NH3 i.e. ammineand H2O i.e. aqua are neutral ligands)

And the anionic part consists of NO3-. Therefore, the formula of complex is [Co(NH3)4(H2O)Cl](NO3)2.

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